Everything electrical so far has assumed a source, and before the generators run, the source is chemical: the battery. This lesson covers what the aircraft battery is for, the four rechargeable chemistries and how they differ, the arithmetic of cells, voltage and capacity, and the hazard that has earned its own paragraph in every modern operations manual: lithium batteries and thermal runaway.
What the battery is for
The aircraft battery is the electrical system's stored reserve, energy held chemically and released as direct current on demand. Its functions follow from that: it powers the aircraft before any generator turns (lighting up the flight deck, running fuel pumps for the start, and supplying the starter itself for the APU or engines); it buffers the running system, absorbing brief dips and spikes while generators and loads switch; and above all it is the final reserve, the source that keeps the essential instruments, radios and computers alive if every generator fails. The battery is sized, checked and kept charged for that last role.
The four chemistries
Four rechargeable battery types serve aviation:
Lead-acid — the traditional aircraft battery: heavy for its energy, tolerant of simple charging, and modest in cost.
Nickel-cadmium (NiCd) — the transport-aviation workhorse: lighter, robust through many cycles, and able to deliver very large currents for engine starting.
Lithium-ion — far more energy for the same weight, used in newer aircraft designs and in nearly every portable device carried aboard.
Lithium-polymer — the same lithium chemistry in a flexible flat pouch instead of a rigid can: lighter and shapeable, but with a soft casing that damage reaches more easily.
The comparison the syllabus asks for runs on three axes:
Load behaviour — how the voltage holds up as current is drawn: lead-acid sags noticeably under heavy load and as it empties; NiCd holds its voltage almost flat until nearly exhausted (excellent for starting, but it gives little voltage warning of a low battery); lithium types also hold up well while delivering the most energy per kilogram.
Charging characteristics — lead-acid accepts simple constant-voltage charging; NiCd charges well but can overheat late in the charge, so aircraft NiCd installations carry temperature monitoring; lithium types demand precisely controlled charging, supervised cell by cell by electronics, because overcharging is one of the routes to runaway.
Risk of thermal runaway — the danger that a hot cell gets hotter by itself: low for lead-acid; real for NiCd (an overheating aircraft NiCd is a known emergency, which the temperature monitoring exists to catch); highest for the lithium types, which pack the most energy into the least material and burn fiercely once started.
Cells, voltage and capacity
Cell voltage is the voltage one electrochemical cell produces, and it is fixed by the chemistry:
Lead-acid — about 2 volts per cell.
NiCd — 1.2 volts per cell.
Lithium-ion — around 3.6 volts per cell.
No single cell suits an aircraft's system, so a battery is built from cells combined: connected in series, their voltages add until the battery reaches the desired voltage (twelve lead-acid cells or twenty NiCd cells make the standard 24-volt aircraft battery), and using larger cells, or groups in parallel, provides the desired capacity.